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=== Using diluted fuel ===
 
=== Using diluted fuel ===
[[File:Advanced-furnace-gas-mixing.png|thumb|gas mixing for 2H2+O2+dilutant]]
+
 
 
Dirty fuel combusts at a lower temperature, the non-combustible gases also helps to increase the pressure. This can be very useful. Adding unreactive gases to a furnace on purpose means that the combustion temperature will be lower and the pressure higher, which helps when making certain alloys. An excess of either oxygen or volatiles will also count as unreactive since they don't take part in the combustion.
 
Dirty fuel combusts at a lower temperature, the non-combustible gases also helps to increase the pressure. This can be very useful. Adding unreactive gases to a furnace on purpose means that the combustion temperature will be lower and the pressure higher, which helps when making certain alloys. An excess of either oxygen or volatiles will also count as unreactive since they don't take part in the combustion.
  
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*P(after) = P(before) * T(after) * ( 1 + 5.7*min(ratio(O2), ratio(H2)*0.5) ) / T(before)
 
*P(after) = P(before) * T(after) * ( 1 + 5.7*min(ratio(O2), ratio(H2)*0.5) ) / T(before)
 
**this expression comes from two sets of PV=nRT, one after and one before combustion. The reaction formula say that for each mol consumed O2 we gain 6 mol gas (9-3), this creates a link between the equations, n(after) = n(before)*(1+min(ratio(O2), ratio(H2)*0.5)*6), then include the 0.95 efficiency as well
 
**this expression comes from two sets of PV=nRT, one after and one before combustion. The reaction formula say that for each mol consumed O2 we gain 6 mol gas (9-3), this creates a link between the equations, n(after) = n(before)*(1+min(ratio(O2), ratio(H2)*0.5)*6), then include the 0.95 efficiency as well
 +
  
 
=== Using Ice(Oxite) and Ice(Volatiles) ===
 
=== Using Ice(Oxite) and Ice(Volatiles) ===
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Observations
 
Observations
*the rate of cooling is temperature dependent, hotter cools faster  
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*the rate of cooling is temperature dependent, hotter cools faster (furnace temp - surrounding temp? how do vaccum behave?)
* Furnaces do not lose heat through conduction if in a vacuum.  This can be very useful for recipes that have tight temperature or pressure windows, although you will have to have an alternate mechanism to tweak the values if you overshoot (such as a valve leading to a pipe with a radiator out in the atmosphere, or a backpressure regulator).
 
 
*the rate of cooling is time dependent (game tick speed is once per 0.5 seconds)
 
*the rate of cooling is time dependent (game tick speed is once per 0.5 seconds)
 
*the rate of cooling is mol dependent (small amounts cool faster)
 
*the rate of cooling is mol dependent (small amounts cool faster)
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*Hold a tablet with an atmos cartridge in the right hand (so it can be read when the game is paused). Aim the tablet against the furnace and pause with ESC, double tap ESC to move the game forward one tick, record the temperatures.
 
*Hold a tablet with an atmos cartridge in the right hand (so it can be read when the game is paused). Aim the tablet against the furnace and pause with ESC, double tap ESC to move the game forward one tick, record the temperatures.
 
*Remember to record the ''total amount of moles'' as well
 
*Remember to record the ''total amount of moles'' as well
 +
  
 
=== Calculating how to reach a desired Temperature and Pressure on ignition ===
 
=== Calculating how to reach a desired Temperature and Pressure on ignition ===
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Reloading the save and placing the furnace inside a welded frame to insulate it (no loss of temperature or pressure) showed the following. The furnace reached 1477K and 19.90MPa after ignition. The fuel was added with a regulator (the furnace showed: 325kPa, 133K), the fuel mix was decent but not a perfect 1:2. Then the diluting O2 was added, it was slightly too cold (the furnace now showed: 1.16MPa, 130K), so a bit too much dilutant was added to the furnace (since cold gas has a lower pressure). The dilutant was inserted via the furnace outlet, checking the mol% with the tablet showed 3% H2 in the outlet pipe and 20% inside the furnace instead of 19% in both, the total number of H2 mol was unchanged. The temperature and pressure was really close to the calculated ones, even though the execution was a bit sloppy. The observed loss of temperature could be explained by using too much dilutant, using a lower starting temperature and a flawed fuel mix. The lower pressure is related to the temperature, going from 1500K to 1477K should mean -1.5% reduction in pressure, but the change was just -0.5%, an indication that too much dilutant had been added.
 
Reloading the save and placing the furnace inside a welded frame to insulate it (no loss of temperature or pressure) showed the following. The furnace reached 1477K and 19.90MPa after ignition. The fuel was added with a regulator (the furnace showed: 325kPa, 133K), the fuel mix was decent but not a perfect 1:2. Then the diluting O2 was added, it was slightly too cold (the furnace now showed: 1.16MPa, 130K), so a bit too much dilutant was added to the furnace (since cold gas has a lower pressure). The dilutant was inserted via the furnace outlet, checking the mol% with the tablet showed 3% H2 in the outlet pipe and 20% inside the furnace instead of 19% in both, the total number of H2 mol was unchanged. The temperature and pressure was really close to the calculated ones, even though the execution was a bit sloppy. The observed loss of temperature could be explained by using too much dilutant, using a lower starting temperature and a flawed fuel mix. The lower pressure is related to the temperature, going from 1500K to 1477K should mean -1.5% reduction in pressure, but the change was just -0.5%, an indication that too much dilutant had been added.
 
 
===Charts for fuel and dilutant mixes at 25°C===
 
 
{| class="wikitable"
 
! colspan="4" |'''Pure fuel at 25°C (perfect mix, 33.33% O2 and 66.67% H2)'''
 
|-
 
! colspan="1" rowspan="1" |'''Temperature (K)'''
 
! colspan="1" rowspan="1" |'''Pressure'''
 
! colspan="1" rowspan="1" |'''Fuel (25°C, 298K)'''
 
! colspan="1" rowspan="1" |'''Comment'''
 
|-
 
| 2481 K
 
| 1.5 MPa
 
| 62 kPa
 
|
 
|-
 
| 2481 K
 
| 22 MPa
 
| 911 kPa
 
|
 
|-
 
| 2481 K
 
| 60 MPa
 
| 2485 kPa
 
| Explosion warning
 
|}
 
 
 
{| class="wikitable"
 
! colspan="6" |'''Perfect fuel diluted with CO2 (specific heat = 28.5, highest value)'''
 
|-
 
! colspan="1" rowspan="1" |'''Temperature (K)'''
 
! colspan="1" rowspan="1" |'''Pressure'''
 
! colspan="1" rowspan="1" |'''Fuel (25°C, 298K)'''
 
! colspan="1" rowspan="1" |'''Dilutant (25°C, 298K)'''
 
! colspan="1" rowspan="1" |'''Fuel + Dilutant (25°C, 298K)'''
 
! colspan="1" rowspan="1" |'''Comment'''
 
|-
 
| 550 K
 
| 1.5 MPa
 
| 34 kPa
 
| 715 kPa
 
| 749 kPa
 
| Will not ignite (must ignite before all dilutant is added)
 
|-
 
| 1200 K
 
| 1.5 MPa
 
| 54.5 kPa
 
| 214.5 kPa
 
| 269 kPa
 
|
 
|-
 
| 1200 K
 
| 22 MPa
 
| 800 kPa
 
| 3144 kPa
 
| 3944 kPa
 
|
 
|-
 
| 1500 K
 
| 19 MPa
 
| 731 kPa
 
| 1655 kPa
 
| 2386 kPa
 
|
 
|}
 
 
 
{| class="wikitable"
 
! colspan="6" |'''Perfect fuel diluted with H2 (specific heat = 20.4, lowest value)'''
 
|-
 
! colspan="1" rowspan="1" |'''Temperature (K)'''
 
! colspan="1" rowspan="1" |'''Pressure'''
 
! colspan="1" rowspan="1" |'''Fuel (25°C, 298K)'''
 
! colspan="1" rowspan="1" |'''Dilutant (25°C, 298K)'''
 
! colspan="1" rowspan="1" |'''Fuel + Dilutant (25°C, 298K)'''
 
! colspan="1" rowspan="1" |'''Comment'''
 
|-
 
| 550 K
 
| 1.5 MPa
 
| 25 kPa
 
| 740 kPa
 
| 765 kPa
 
| Will not ignite (must ignite before all dilutant is added)
 
|-
 
| 1200 K
 
| 1.5 MPa
 
| 44.5 kPa
 
| 243.5 kPa
 
| 288 kPa
 
|
 
|-
 
| 1200 K
 
| 22 MPa
 
| 652 kPa
 
| 3572 kPa
 
| 4224 kPa
 
|
 
|-
 
| 1500 K
 
| 19 MPa
 
| 624 kPa
 
| 1966 kPa
 
| 2590 kPa
 
|
 
|}
 

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